全文获取类型
收费全文 | 61121篇 |
免费 | 9772篇 |
国内免费 | 4107篇 |
专业分类
电工技术 | 2790篇 |
技术理论 | 1篇 |
综合类 | 5484篇 |
化学工业 | 14813篇 |
金属工艺 | 7379篇 |
机械仪表 | 3776篇 |
建筑科学 | 1715篇 |
矿业工程 | 1386篇 |
能源动力 | 1362篇 |
轻工业 | 2026篇 |
水利工程 | 482篇 |
石油天然气 | 1101篇 |
武器工业 | 565篇 |
无线电 | 5478篇 |
一般工业技术 | 14234篇 |
冶金工业 | 3228篇 |
原子能技术 | 485篇 |
自动化技术 | 8695篇 |
出版年
2024年 | 139篇 |
2023年 | 1383篇 |
2022年 | 1497篇 |
2021年 | 2350篇 |
2020年 | 2409篇 |
2019年 | 2440篇 |
2018年 | 2222篇 |
2017年 | 2630篇 |
2016年 | 2777篇 |
2015年 | 3146篇 |
2014年 | 3676篇 |
2013年 | 4266篇 |
2012年 | 4162篇 |
2011年 | 4290篇 |
2010年 | 3353篇 |
2009年 | 3630篇 |
2008年 | 3206篇 |
2007年 | 3883篇 |
2006年 | 3532篇 |
2005年 | 3180篇 |
2004年 | 2635篇 |
2003年 | 2472篇 |
2002年 | 1944篇 |
2001年 | 1653篇 |
2000年 | 1414篇 |
1999年 | 1123篇 |
1998年 | 960篇 |
1997年 | 732篇 |
1996年 | 703篇 |
1995年 | 618篇 |
1994年 | 530篇 |
1993年 | 403篇 |
1992年 | 345篇 |
1991年 | 290篇 |
1990年 | 290篇 |
1989年 | 222篇 |
1988年 | 116篇 |
1987年 | 67篇 |
1986年 | 47篇 |
1985年 | 49篇 |
1984年 | 42篇 |
1983年 | 44篇 |
1982年 | 28篇 |
1981年 | 17篇 |
1980年 | 9篇 |
1979年 | 8篇 |
1978年 | 9篇 |
1977年 | 11篇 |
1975年 | 8篇 |
1951年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 171 毫秒
41.
《Ceramics International》2022,48(10):13927-13937
Long-term thermal cycling causes irreversible dimensional changes of the material, which in turn affects the reliability of precision instruments. In this paper, dimensional stability mechanisms of SiC/Al composites during thermal cycling were revealed using high-precision thermal dilatometer, XRD and spherical aberration correction transmission electron microscope (Cs-TEM). First, how the factors including dislocations, internal stress and precipitates affect the dimensional change of SiC/Al composites were separately introduced. Then, the integrated effect of these factors affecting the dimensional stability of SiC/Al composites was further discussed. Among them, the integrated effect of dislocation-internal stress in SiC/pure Al composites leads to an increase in dislocation density and average lattice constant, which leads to an increase in dimensional change. The integrated effect of dislocation-internal stress-precipitates in SiC/2024Al composites leads to a decrease in the average lattice constant and some changes in the precipitation behavior (including the type, density and lattice constant of the precipitates), which ultimately leads to a decrease in dimensional change. The dimensional change of the two types of composites was semi-quantitatively estimated. Finally, the reasons for the significantly higher dimensional stability of the SiC/2024Al composites were given. 相似文献
42.
《Ceramics International》2022,48(12):16923-16932
This paper offers a new way of testing the ablation property of material under an oxyacetylene torch using a thin-blade specimen, which costs much less time to reach the maximum temperature and provides a harsh turbulence fluid field that's closer to reality. The thin-blade specimen experiences a higher turbulent intensity than the traditional disk-like specimen, leading to more efficient heat exchange. The fluid field simulation agrees with the testing results. In addition, we manage to synthesize the C/Cx-SiCy composites with the co-deposition chemical vapor infiltration (CVI) method. The C/Cx-SiCy composites exhibit a similar anti-ablation property as C/C composites and consist of enough SiC phase simultaneously, combining the advantages of both C/C composites and C/SiC composites. The thin-blade C/Cx-SiCy composites show a lower linear ablation rate (1.6 μm/s) than C/C composites (4.1 μm/s) and C/SiC composites (19.6 μm/s) during the oxyacetylene test. The glass layer formed on the surface of C/Cx-SiCy could cling to the bulk material instead of peeling off due to the high PyC content in the matrix could protect the SiO2 from blowing away. 相似文献
43.
44.
以富氮羧酸类分子2,2'-(3,3'-偶氮-双(1H-1,2,4-三唑-5基))二乙酸(H2DTDA)与氢氧化锶八水合物为原料,在水热条件下制备了一种金属有机框架(MOF)结构的新型红色烟火着色剂[Sr_2(DTDA)(H_2O)_6]_n(1);采用傅里叶变换红外光谱(FT-IR)、X射线单晶衍射(XRD)、粉末X射线单晶衍射(PXRD)和元素分析等对化合物结构进行了表征;采用热重法(TG)-差示扫描量热法(DSC)、BAM标准法测试了化合物1的热性能和感度性能;设计了烟火剂配方,对化合物1应用于红色烟火着色剂的可行性进行分析。结果表明,化合物1是一种具有二维空间结构的MOF材料,其层状结构之间存在丰富的氢键作用;放大合成的水热实验同样可以得到高纯度的化合物1;撞击感度为80 J,摩擦感度 360 N;化合物1可作为红色着色剂应用于烟火剂配方中。 相似文献
45.
Expanded graphite (EG) is introduced into poly(vinylidene fluoride) (PVDF) by melt mixing extrusion with water injection. The results demonstrate that the unfunctionalized EG in composite prepared with water injection exbibits better dispersion than that in the one prepared without water injection due to the promoting role of water during extrusion. Thus, the PVDF/EG composite with loading of 4 wt% prepared by water‐assisted mixing extrusion (WAME) exhibits electrical conductivity of about three orders of magnitude higher than the neat PVDF and one order of magnitude higher than the one prepared without water injection. Comparing to the neat PVDF, the thermal conductivity of the composites prepared with and without water injection is increased by 101.5% and 75.0%, respectively. The introduced EG leads to increased Young’s modulus and tensile strength especially for the composite prepared by WAME. The present work indicates that WAME can promote the dispersion of EG in PVDF matrix without any extra functionalization. 相似文献
46.
Youcef Hadji Abdessabour Benamor Nabil Chiker Adel Haddad Nacer Tala-Ighil Jean-Pierre Erauw Vedi Dupont Arnaud Tricoteaux Christelle Nivot Anthony Thuault Mohamed Hadji 《International Journal of Applied Ceramic Technology》2020,17(2):695-706
In this study, wear and friction behavior of two based-composites from the Ti-Si-C system, (40 wt% TiC; 28 wt% Ti5Si3; 17 wt% Ti3SiC2) and (18 wt% TiC; 26 wt% Ti5Si3; 41 wt% Ti3SiC2) reinforced by 15 wt% of large size SiC (100-150 µm) particles were investigated. The four-phase composites exhibited approximatively the same friction coefficient (µ ~ 0.9) under high loads (10 N and 7 N). The composite with high Ti3SiC2 showed higher wear rate values by one order of magnitude. However, under 1 N, the composite with high TiC content showed a higher running-in period and a lower steady state µ value (0.37 after 1000 m sliding distance). Scanning electron microscopy, Energy Dispersive X-Ray and Raman spectroscopy analysis of the worn surfaces of the two composites revealed that oxidation was the dominant wear mechanism. The oxidation process and the removal kinetics of the oxides during sliding controlled the tribological behavior of the composites. The influence of processing variables on microstructures development and wear mechanisms of the composites is discussed. 相似文献
47.
以无水氯化镁和氧化镁作为中间产物,电解和热还原为两个关键方法,集成各种相关过程,构建了从水氯镁石到金属镁的综合过程网络,其中涉及24个物种、20个化学过程和25个工艺路线;建立了最低能耗分析模型用于简单和复合过程的能量分析;利用物质的标准生成焓和多温等压摩尔热容,计算得出全部反应过程及工艺过程的能量消耗和热量移除。结果表明基于还原法的最优路径是水氯镁石用石灰法转为氢氧化镁,进而煅烧成氧化镁,再铝热还原成金属镁,该过程能耗360.15 kJ/mol,放出热量–315.46 kJ/mol;基于电解法的最优路径是石灰乳法生成氢氧化镁,再煅烧成氧化镁,通过在熔融电解质中电解生成金属镁,该过程能耗738.54 kJ/mol,放出热量–135.42 kJ/mol。无水氯化镁制备耗能高,不在最优路径中。 相似文献
48.
利用放电等离子烧结(SPS)技术制备了HA/Ti-24Nb-4Zr生物复合材料,研究了不同退火温度对复合材料显微组织和力学性能(抗压强度、屈服强度、屈强比、压缩弹性模量)的影响。结果表明,烧结态复合材料主要由β-Ti相、少量初生α-Ti相及HA相组成;随着退火温度的升高,复合材料基体中β-Ti相含量增多且晶粒逐渐长大,针状次生α-Ti相在晶界处和晶内不断析出,HA相结构和含量变化不大;与烧结态相比,不同退火温度处理后的复合材料强度和弹性模量先略微上升后下降,而塑韧性呈不断提高趋势;复合材料在850 ℃退火处理后,抗压强度、屈服强度、屈强比和压缩弹性模量值分别为1507 MPa、1270 MPa、0.84和42 GPa,塑韧性得到明显改善,作为生物医用植入材料具有潜在的应用前景。 相似文献
49.
50.
针对我国水资源紧缺、水生态损害、水环境污染等相关水问题,以提升全民爱水惜水节水护水的意识和能力为目标,从水素养概念出发,通过扎根理论质性研究方法对公民水素养评价的表征因素进行筛选和提炼,最终得出包含水知识、水态度、水行为为主范畴的10个表征因素并运用解释结构模型(ISM)深入剖析各因素之间的内在联系。在此基础上建立了3级多层次递阶结构模型,进一步精确描述系统各要素两两之间的直接关系。结果表明:公民水素养评价的表征因素自上而下形成了表象层、中间层和根源层等3个层级,可直观、清晰地反映表征因素之间的递阶、层级关系;水态度在各表征因素中具有调节作用以及各表征因素之间存在内在逻辑关系。研究成果为提高公民水素养水平提供一定的科学依据和政策参考。 相似文献